The Gaseous Explosive Reaction : the Effect of Pressure on the Rate of Propagation of the Reaction Zone and upon the Rate of Molecular Transformation (1932)
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f molecular trans- formation during the progress of the reaction in the bomb depends on three factors: (1) The linear rate at which the active gaseous components pass the reac- tion zone (the rate of propagation of the zone within the gases); (2) upon the partial pressure (concentra- tion) of the… … Figure 7 transformation increases with the pressure, and by (3) the effective area of the zone increases as the square of its radius, it would follow^ that the total rate of molecular reaction should increase rapidly as the transformation proceeds from ignition, reaching its maximum value during…
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